It’s actually a scene from Havoc, and the highlights didn’t really look very green on screen. Exaggerated color sometimes occurs when an imager changes the levels and/or increases the saturation to make a dark picture look brighter.
This was our top nude scene of 2005. That was her year. She also had the 15th-place winner that same year, for Brokeback Mountain
…a .gif from Brokeback Mountain
Hathaway also had the top nude scene of 2010 (actually tied for first – our only tie), with Love and Other Drugs.
Away from the movie cameras, she once underestimated the effect of bright lights on her top.